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虎门体育官方登录入口网:Deformable fibrous carbon supported ultrafine nano-SnO2 as a high volumetric capacity and cyclic durable anode for Li storage

时间:2018-05-25作者:浏览量:99


虎门体育官方登录入口网:标题

Deformable fibrous carbon supported ultrafine nano-SnO2 as a high volumetric capacity and cyclic durable anode for Li storage

虎门体育官方登录入口网:作者

作者:Hu, RZ (Hu, Renzong)[1,2 ]; Zhang, HY (Zhang, Hanyin)[1 ]; Liu, JW (Liu, Jiangwen)[1 ]; Chen, DC (Chen, Dongchang)[2 ]; Yang, LC (Yang, Lichun)[1 ]; Zhu, M (Zhu, Min)[1 ]; Liu, ML (Liu, Meilin)[2 ]

虎门体育官方登录入口网:期刊信息


JOURNAL OF MATERIALS CHEMISTRY A


卷:3

期:29

页:15097-15107

DOI:10.1039/c5ta03401a

出版年:2015

文献类型:Article

查看期刊影响力

虎门体育官方登录入口网:摘要

Multidimensional fibrous carbon scaffolds, derived from carbonized filter papers (CFPs), were used to support SnO2 nanocrystals (NCs, with a size of 4-5 nm) to form a free-standing SnO2NC@CFP hybrid anode for Li-ion batteries. The SnO2NC particles are well accreted on the surfaces of 1D carbon fibers and 2D ultrathin carbon sheets while maintaining 3D interconnected pores of the carbon matrices for fast ionic transport. The SnO2NC@CFP hybrid electrode exhibits long-term higher energy density than the commercial graphite anode, and excellent rate capability, mainly due to good dispersion of SnO2 in the multidimensional conductive carbon. In particular, the reversible deformation of the flexible fibrous carbon matrices, as inferred from in situ Raman spectroscopy and SEM image analysis, facilitates stress release from the active SnO2NCs during discharge-charge cycling while maintaining the structural integrity of the self-supported SnO2NC@CFP anode. These demonstrate that the rational combination of the multidimensional architecture of deformable carbon with nanoscale active materials is ideally suited for high-performance Li-ion batteries.

虎门体育官方登录入口网:关键词

KeyWords Plus:LITHIUM-ION BATTERIES; ONE-POT SYNTHESIS; SNO2/GRAPHENE COMPOSITE; GRAPHENE SHEETS; AMORPHOUS OXIDE; TIN OXIDE; ELECTRODE; SN; NANOCOMPOSITE; NANOPARTICLES

虎门体育官方登录入口网:作者信息

作者信息

通讯作者地址:Zhu, M (通讯作者)

显示更多S China Univ Technol, Sch Mat Sci & Engn, Guangdong Prov Key Lab Adv Energy Storage Mat, Guangzhou 510640, Peoples R China.


地址:

显示更多[ 1 ] S China Univ Technol, Sch Mat Sci & Engn, Guangdong Prov Key Lab Adv Energy Storage Mat, Guangzhou 510640, Peoples R China
显示更多[ 2 ] Georgia Inst Technol, Sch Mat Sci & Engn, Atlanta, GA 30332 USA


电子邮件地址:memzhu@scut.edu.cn; meilin.liu@mse.gatech.edu

虎门体育官方登录入口网:出版商

ROYAL SOC CHEMISTRY, THOMAS GRAHAM HOUSE, SCIENCE PARK, MILTON RD, CAMBRIDGE CB4 0WF, CAMBS, ENGLAND

虎门体育官方登录入口网:类别分类

类别 / 分类

研究方向:Chemistry; Energy & Fuels; Materials Science

Web of Science 类别:Chemistry, Physical; Energy & Fuels; Materials Science, Multidisciplinary

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